On the theory of electrochemical and chemical electron. Marcus, chemical and electrochemical electrontransfer theory, nov. One of the active areas in reaction kinetics during the postwar years has been that of electrontransfer reactions. Electron transfer et is one of the most ubiquitous and fundamental phenomena in chemistry, physics, and.
Chemical and electrochemical electrontransfer theory. Chemical and electrochemical electrontransfer theory request. Observations and theories of quantum effects in proton transfer. The reorganization energy, which is a measure of the freeenergy change associated with solute and solvent rearrangements, is a key quantity for calculating rate constants for these reactions. The chemical reactions also represent one of the ve. On the theory of electrochemical and chemical electron transfer processes. Abstract electron transfer across the moleculesemiconductor interface is a fundamental process that is relevant to many applications of nanoparticles, such as dyesensitized solar cells and molecular electronics. These reactions constitute one type of oxidationreduction process and include both chemical and electrochemical systems.